Magnetic properties and magnetocaloric effects of manganite (La_(0.8)Ho_(0.2))_(2/3)Ca_(1/3)MnO_3 and (La_(0.5)Ho_(0.5))_(2/3)Ca_(1/3)MnO_3  

作　　者：何宁 祁阳 张彩碚 

机构地区：[1]Institute of Materials Physics and Chemistry,School of Sciences,Northeastern University [2]China Medical University [3]Key Laboratory for Anisotropy and Texture of Materials of Ministry of Education,Northeastern University

出　　处：《Journal of Rare Earths》2010年第S1期413-416,共4页稀土学报（英文版）

基　　金：Project supported by the National Natural Science Foundation of China (50572013)

摘　　要：We reported the magnetic properties and magnetocaloric effects(MCE) of(La0.8Ho0.2)2/3Ca1/3MnO3 and(La0.5Ho0.5)2/3Ca1/3MnO3 nanoparticles by sol-gel technique.With this method,we were able to obtain the samples with particle diameters ranging from 50 to 200 nm.In the(La1-xHox)2/3Ca1/3MnO3 compound,an external magnetic field induced a magnetic transition from an paramagnetic phase to a ferromagnetic phase above Ts=105-135 K,leading to magnetocaloric effects.The maximum value of ΔSM was 1.19 J/(kg·K) at 100 K and 2.03 J/(kg·K) at 152 K for a magnetic field change of 5 T.Because both samples had large relative cooling power(RCP) and wide δTFWHM,the study on systems with the(La1-xHox)2/3Ca1/3MnO3-related magnetic transitions may open an important field in searching good magnetic materials.We reported the magnetic properties and magnetocaloric effects(MCE) of(La0.8Ho0.2)2/3Ca1/3MnO3 and(La0.5Ho0.5)2/3Ca1/3MnO3 nanoparticles by sol-gel technique.With this method,we were able to obtain the samples with particle diameters ranging from 50 to 200 nm.In the(La1-xHox)2/3Ca1/3MnO3 compound,an external magnetic field induced a magnetic transition from an paramagnetic phase to a ferromagnetic phase above Ts=105-135 K,leading to magnetocaloric effects.The maximum value of ΔSM was 1.19 J/(kg·K) at 100 K and 2.03 J/(kg·K) at 152 K for a magnetic field change of 5 T.Because both samples had large relative cooling power(RCP) and wide δTFWHM,the study on systems with the(La1-xHox)2/3Ca1/3MnO3-related magnetic transitions may open an important field in searching good magnetic materials.

关 键 词：sol-gel magnetocaloric effects perovsvskites relative cooling power (RCP) rare earths 

分 类 号：TG132.2[一般工业技术—材料科学与工程]