Kinetic theory of self-condensing vinyl polymerization  

作　　者：ZHOU ZhiPing 1 & YAN DeYue 2 1 School of Materials Science and Engineering,Jiangsu University,Zhenjiang 212013,China 2 School of Chemistry and Chemical Engineering,Shanghai Jiao Tong University,Shanghai 200240,China 

出　　处：《Science China Chemistry》2010年第12期2429-2439,共11页中国科学（化学英文版）

基　　金：supported by the National Natural Science Foundation of China(20774038,50633010 & 20874060)

摘　　要：This review introduces the kinetic theory of self-condensing vinyl polymerization (SCVP),including the SCVP of AB inimers,the SCVP with non-equal reactivity between A and B groups,the SCVP in the presence of a small amount of multifunctional initiators,also the SCVP of both inimers and comonomers.The analytical expressions of various molecular parameters for the resulting hyperbranched polymers,such as the molecular size distribution function,the average molecular weight,the polydispersity index and the degree of branching,are reviewed systematically.This review introduces the kinetic theory of self-condensing vinyl polymerization (SCVP),including the SCVP of AB inimers,the SCVP with non-equal reactivity between A and B groups,the SCVP in the presence of a small amount of multifunctional initiators,also the SCVP of both inimers and comonomers.The analytical expressions of various molecular parameters for the resulting hyperbranched polymers,such as the molecular size distribution function,the average molecular weight,the polydispersity index and the degree of branching,are reviewed systematically.

关 键 词：KINETIC THEORY self-condensing VINYL POLYMERIZATION (SCVP) HYPERBRANCHED POLYMERS 

分 类 号：O631.3[理学—高分子化学]