Catalytic selective oxidation or oxidative functionalization of methane and ethane to organic oxygenates  

作　　者：WANG Ye AN DongLi ZHANG QingHong 

机构地区：[1]State Key Laboratory of Physical Chemistry of Solid Surfaces,National Engineering Laboratory for Green Chemical Productions of Alcohols,Ethers and Esters,Department of Chemistry,College of Chemistry and Chemical Engineering,Xiamen University,Xiamen 361005,China

出　　处：《Science China Chemistry》2010年第2期337-350,共14页中国科学(化学英文版)

基　　金：Financial support by the National Natural Science Foundation of China (Grant Nos. 20433030, 20625310, 20773099 and 20873110);the National Basic Program of China (Grant Nos. 2005CB221408 and 2010CB732303);the Key Scientific Project of Fujian Province (2009HZ0002-1);the Program for New Century Excellent Talents in Fujian Province (to Q. Z.)

摘　　要：Selective oxidation or oxidative functionalization of methane and ethane by both homogeneous and heterogeneous catalysis is presented concerning: (1) selective oxidation of methane and ethane to organic oxygenates by hydrogen peroxide in a water medium in the presence of homogeneous osmium catalysts, (2) selective oxidation of methane to formaldehyde over highly dispersed iron and copper heterogeneous catalysts, (3) selective oxidation of ethane to acetaldehyde and formaldehyde over supported molybdenum catalysts, and (4) oxidative carbonylation of methane to methyl acetate over heterogeneous catalysts containing dual sites of rhodium and iron.Selective oxidation or oxidative functionalization of methane and ethane by both homogeneous and heterogeneous catalysis is presented concerning: (1) selective oxidation of methane and ethane to organic oxygenates by hydrogen peroxide in a water medium in the presence of homogeneous osmium catalysts, (2) selective oxidation of methane to formaldehyde over highly dispersed iron and copper heterogeneous catalysts, (3) selective oxidation of ethane to acetaldehyde and formaldehyde over supported molybdenum catalysts, and (4) oxidative carbonylation of methane to methyl acetate over heterogeneous catalysts containing dual sites of rhodium and iron.

关 键 词：METHANE ETHANE C-H bond activation selective oxidation oxidative functionalization heterogeneous catalysis homogeneous catalysis 

分 类 号：O621.25[理学—有机化学]