Synthesis of two new cage molecules containing trinitromethyl group  

作　　者：Cheng Hui Sun Xin Qi Zhao Yu Chuan Li Si Ping Pang 

机构地区：[1]School of Material Science&Engineering,Beijing Institute of Technology,Beijing 100081,China

出　　处：《Chinese Chemical Letters》2010年第5期572-575,共4页中国化学快报(英文版)

基　　金：the National Natural Science Foundation of China(No.20772011);the Basic Research Foundation of Beijing Institute of Technology(No.3090050320906) for financial support for this work.

摘　　要：Two new cage compounds,4-trinitroethyl-10-nitro-2,6,8,12-tetraacetylhexaazaisowurtzitane（3） and 4-trinitroethyl- 2,6,8,10,12-pentanitrohexaazaisowurtzitane（4）,containing trinitromethyl group were synthesized by a novel method,and their structures were confirmed by IR,;H NMR,MS and single crystal X-ray.DSC result shows that compound 4 has surprising thermal stability and could be a potential energetic compound.Two new cage compounds,4-trinitroethyl-10-nitro-2,6,8,12-tetraacetylhexaazaisowurtzitane(3) and 4-trinitroethyl- 2,6,8,10,12-pentanitrohexaazaisowurtzitane(4),containing trinitromethyl group were synthesized by a novel method,and their structures were confirmed by IR,~1H NMR,MS and single crystal X-ray.DSC result shows that compound 4 has surprising thermal stability and could be a potential energetic compound.

关 键 词：Cage compound Trinitromethyl group SYNTHESIS X-ray crystal structure 

分 类 号：O626.2[理学—有机化学]