Tandem Lewis acid catalyzed coupling/semipinacol rearrangement of allylic alcohol  

作　　者：YUAN DaoYi,ZHANG YongQiang,TU YongQiang,CHEN ZhiHua & ZHAO Xiong State Key Laboratory of Applied Organic Chemistry Department of Chemistry,Lanzhou University,Lanzhou 730000,China 

出　　处：《Science China Chemistry》2010年第1期147-150,共4页中国科学（化学英文版）

基　　金：supported by the National Natural Science Foundation of China (Grant Nos. 20621091,20672048,and 20732002);the "111" program of Chinese Education Ministry

摘　　要：Construction of the polyaryl quaternary unit through a ZnBr2 catalyzed tandem coupling/semipinacol rearrangement participated by allylic cations was reported for the first time.Construction of the polyaryl quaternary unit through a ZnBr2 catalyzed tandem coupling/semipinacol rearrangement participated by allylic cations was reported for the first time.

关 键 词：COUPLING semipinacol REARRANGEMENT ALLYLIC CATION QUATERNARY center 

分 类 号：O643.32[理学—物理化学]