两种对甲氧基苄基腺嘌呤类化合物的合成及表征  

Synthesis and characterization of two kinds of p-methoxybenzyl adenine derivatives

作　　者：孙文阳[1] 梁镇海[1] 韩灵翠[1] 

机构地区：[1]太原理工大学化学化工学院,山西太原030024

出　　处：《现代化工》2009年第S1期329-331,333,共4页Modern Chemical Industry

基　　金：山西省农社科技攻关资助项目(051039-3)

摘　　要：以对甲酚为原料,经对甲苯甲醚、对甲氧基苄基溴,再与腺嘌呤缩合,合成了N6,N9-二(对甲氧基苄基)腺嘌呤和N6,N6,N9-三(对甲氧基苄基)腺嘌呤,利用红外光谱、核磁共振和质谱等检测手段对化合物的结构进行了表征,用萝卜子叶增重法测定了化合物的细胞分裂素活性,证明了2种对甲氧基苄基腺嘌呤类化合物都具有生物活性。Two new compounds,N6,N9-di(p-methoxybenzyl)adenine and N6,N9,N9-tri(p-methoxybenzyl)adenine,are synthesized by three steps of reactions as follows:from 4-methoxytoluene to 4-methylanisole,then to 4-methoxybenzyl bromide,and finally the prepared product condense with adenine.Their structures are characterized by IR,1H-NMR and MS,their activities of cytokinins are determined with radish cotyledons weight adding method,and the results prove that p-methoxybenzyl adenine derivatives have bioactivities.

关 键 词：N6 N9-二(对甲氧基苄基)腺嘌呤 N6 N6 N9-三(对甲氧基苄基)腺嘌呤 腺嘌呤 对甲氧基苄基溴 

分 类 号：S482.8[农业科学—农药学]