Rheological behavior during thermotropic gelation of polyacrylonitrile concentrated solutions  

作　　者：马彩霞 闫伟霞 张莉 秦宗益 潘鼎 

机构地区：[1]State Key Laboratory for Chemical Fibers Modification and Polymer Materials,Donghua University [2]Research Centre for Analysis and Measurement,Donghua University

出　　处：《Journal of Central South University》2008年第S1期122-125,共4页中南大学学报（英文版）

基　　金：Project(2006CB606505) supported by the National Basic Research Development Program of China;Project(50333050) supported by the National Natural Science Foundation of China;Project(07DJ14002) supported by the Shanghai Fundamental Theory Program;Project(20020255010) supported by the Specialized Research Fund for the Doctoral Program of Higher Education

摘　　要：Dynamic viscoelastic properties of polyacrylonitrile(PAN)/DMSO/H2O solutions with different H2O contents were studied as a function of temperature.These PAN solutions gradually became gel with decreasing temperature.The sol-gel transition took place at a critical gel temperature,at which the scaling law of G'(ω)～G″(ω)∝ωn held,allowing an accurate determination of the critical gel temperature by means of the frequency independence of the loss tangent.The gel point of PAN solutions increases with increasing H2O content.The scaling exponent n(=0.86) at the gel point is confirmed to be universal for PAN gels,which is independent of temperature,suggesting the similarity of the fractal structure in the critical PAN gels.Dynamic viscoelastic properties of polyacrylonitrile(PAN)/DMSO/H2O solutions with different H2O contents were studied as a function of temperature. These PAN solutions gradually became gel with decreasing temperature. The sol-gel transition took place at a critical gel temperature, at which the scaling law of G′(ω)～G″(ω)∝ω n held, allowing an accurate determination of the critical gel temperature by means of the frequency independence of the loss tangent. The gel point of PAN solutions increases with increasing H2O content. The scaling exponent n (=0.86) at the gel point is confirmed to be universal for PAN gels, which is independent of temperature, suggesting the similarity of the fractal structure in the critical PAN gels.

关 键 词：POLYACRYLONITRILE GEL POINT THERMOTROPIC GELATION RHEOLOGICAL behavior 

分 类 号：O631.3[理学—高分子化学]