Synthesis and Characterization of a Series of New Functional Poly(ferrocenylenesilanes) for Nonlinear Optics  

作　　者：刘云阳 张萱 唐红定 王婷娟 秦金贵 刘道玉 李绍军 叶成 

出　　处：《Chinese Journal of Chemistry》2002年第11期1199-1204,1126,共6页中国化学（英文版）

基　　金：theEducationMinistryofChinaandbyagrant (No .990 78)fromtheNationalKeyFundamentalResearchPro gramofChina

摘　　要：A series of new poly(ferrocenylenesilanes) containing carbazole as charge transporting agent and Dispersed Red 1 (DR-1) as second-order nonlinear optical (NLO) chromophore was synthesized. The resulting polymers represent the first example of NLO polymer with ferrocenyl groups in the backbone. This series of polymers was characterized with H-1 NMR, UV-vis, IR spectroscopies, differential scanning calorimeter (DSC) and gel permeation chromatography (GPC). A preliminary measurement on NLO property of the polymers was carried out with in-situ second-harmonic generation (SHG) measurement.A series of new poly(ferrocenylenesilanes) containing carbazole as charge transporting agent and Dispersed Red 1 (DR-1) as second-order nonlinear optical (NLO) chromophore was synthesized. The resulting polymers represent the first example of NLO polymer with ferrocenyl groups in the backbone. This series of polymers was characterized with H-1 NMR, UV-vis, IR spectroscopies, differential scanning calorimeter (DSC) and gel permeation chromatography (GPC). A preliminary measurement on NLO property of the polymers was carried out with in-situ second-harmonic generation (SHG) measurement.

关 键 词：poly(ferrocenylenesilane) nonliner optical (NLO) PHOTOREFRACTIVE MULTIFUNCTIONAL synthesis CHROMOPHORE SHG 

分 类 号：O634[理学—高分子化学]