Synthesis and Characterization of 2,6-Bis(imino)phenoxy Cobalt Complexes  

作　　者：韩玲芹 孙文华 王乐勇 邵长星 王宏根 李记太 

出　　处：《Chinese Journal of Chemistry》2002年第12期1523-1528,1461,共6页中国化学（英文版）

基　　金："OnehundredTalents"andCoreResearchforEngineeringInnovationKGCX2 0 3 2

摘　　要：A series of cobalt complexes bearing 2,6-bis(imino) phenoxy ligands, LCoCl2 [L = 2,6-(ArNCH)2CH3C6H2OH] was synthesized by the reaction of the ligand 2,6-bis (imino) phenol with the equivalent mole of cobalt dichloride, and these complexes were characterized by elemental analyses, 1H NMR, MS and IR spectra. The structure of one complex was determined by single crystal X-ray diffraction analysis.A series of cobalt complexes bearing 2,6-bis(imino) phenoxy ligands, LCoCl2 [L = 2,6-(ArNCH)2CH3C6H2OH] was synthesized by the reaction of the ligand 2,6-bis (imino) phenol with the equivalent mole of cobalt dichloride, and these complexes were characterized by elemental analyses, 1H NMR, MS and IR spectra. The structure of one complex was determined by single crystal X-ray diffraction analysis.

关 键 词：cobalt complex SCHIFF-BASE crystal structure 

分 类 号：O627[理学—有机化学]