Synthesis of a Soluble Diacetylene with Phenylimidazole Ring  

作　　者：WANG Jiang-hong, CAO Ya-an, CAO Chang-sheng, SHI Yan-hui SHONG Qing, WANG Li-jun and YAO Jian-nian (Institute of Photographic Chemistry, Chinese Academy of Sciences, Beijing 100101, P. R. China  Department of Chemistry, Jilin University, Changchun 130023, 

出　　处：《Chemical Research in Chinese Universities》2000年第4期324-327,共4页高等学校化学研究（英文版）

基　　金：Supported by the " 95" Key Project of Chinese Academy of Sciences Specially and the National Natural ScienceFoundation of Chin

摘　　要：6-(2-Methyl-4-phenyl)-N-imidazole-2, 4-hexadiyn-1-ol was synthesized in a good yield by asymmetric coupling, and the corresponding intermediates were also prepared. The diacetylene monomer could be dissolved in common organic solvents. In addition, all kinds of conditions were also discussed effectively improving the formation of the diacetylene monomer.6-(2-Methyl-4-phenyl)-N-imidazole-2, 4-hexadiyn-1-ol was synthesized in a good yield by asymmetric coupling, and the corresponding intermediates were also prepared. The diacetylene monomer could be dissolved in common organic solvents. In addition, all kinds of conditions were also discussed effectively improving the formation of the diacetylene monomer.

关 键 词：Asymmetric coupling Phenylimidazole Ring POLYDIACETYLENE 

分 类 号：O626[理学—有机化学]