Crystal Structure of N-Phenylisothiocyanatido-Phosphonamidothioate  

作　　者：HE Liang-Nian  CHEN Ru-Yu(Institute of Elemento-Organic Chemistry, Nankai University, Tianjin 300071)WANG Hong-Gen YAO Xin-Kan(Central Laboratory, Nankai University, Tianjin 300071) 

出　　处：《Chinese Journal of Structural Chemistry》1997年第3期200-202,共3页结构化学（英文）

摘　　要：The crystal structure of the title compound, C14H13N2OPS2, has beendetermined by single crystal X-ray diffraction at 299(±1 )K. The crystal is monoclinicwith space group P21/n, a= 11. 310(2), b=8. 363(3), c= 16. 847(4) A, β= 105. 01(2)°, V= 1539(1) A3, Z=4, Dx= 1. 38g/cm3, μ(M0Ka) = 0. 43mm-1, Mr= 320. 7,F(000) = 644. The final R factor is 0. 051, and R. is 0.052. The result of X-raydiffraction analysis indicates that the atoms P.S(2) 1 N (2).C(11) and N (1) constitutea distorted tetrahedron with sp3 hybridized phosphorus atom in the center.The crystal structure of the title compound, C14H13N2OPS2, has beendetermined by single crystal X-ray diffraction at 299(±1 )K. The crystal is monoclinicwith space group P21/n, a= 11. 310(2), b=8. 363(3), c= 16. 847(4) A, β= 105. 01(2)°, V= 1539(1) A3, Z=4, Dx= 1. 38g/cm3, μ(M0Ka) = 0. 43mm-1, Mr= 320. 7,F(000) = 644. The final R factor is 0. 051, and R. is 0.052. The result of X-raydiffraction analysis indicates that the atoms P.S(2) 1 N (2).C(11) and N (1) constitutea distorted tetrahedron with sp3 hybridized phosphorus atom in the center.

关 键 词：isothiocyanatidophosphonamidothioate crystal structure Lawesson's reagent 

分 类 号：O76[理学—晶体学]