Crystal Structure of 2-Germatranylmethyl-N-(4'-methylphenyl) succinimide  

作　　者：ZHANG Zhong-Biao CHEN Ru-Yu(Institute of Elemento-Organic Chemtary,Nankai University, Tianjin 300071)WANG Hong-Gen(Central Laboratory, Nankai University, Tianjin 300071) 

出　　处：《Chinese Journal of Structural Chemistry》1997年第3期203-206,共4页结构化学（英文）

摘　　要：The title crystal of 2-germatranylmethyl-N- (4'-methylphenyl)succinimide (C18H24GeN2O5) was determined by single crystal X-ray diffraction- The crystalbelongs to the orthorhombic system, space group P212121 with Mr = 420. 99, a= 6. 716(1), b=22- 860(8), c= 11. 891 (3) A, V= 1826(1) A3, Z=4,Dx= 1. 53 Mg. m-3,A= 0. 71073A, μ= 1. 684 mm-l, and F(000) =872. The structure was solved by direct methods. The final refinement is converged with unweighted and weighted agreement factors of 0. 047 and 0. 064 for 1610 observed reflections with I≥3δ(I). The results of structure analysis indicate that the framework of this five-coordinated germanium compound is a distorted trigonal bipyramid(TBP).The title crystal of 2-germatranylmethyl-N- (4'-methylphenyl)succinimide (C18H24GeN2O5) was determined by single crystal X-ray diffraction- The crystalbelongs to the orthorhombic system, space group P212121 with Mr = 420. 99, a= 6. 716(1), b=22- 860(8), c= 11. 891 (3) A, V= 1826(1) A3, Z=4,Dx= 1. 53 Mg. m-3,A= 0. 71073A, μ= 1. 684 mm-l, and F(000) =872. The structure was solved by direct methods. The final refinement is converged with unweighted and weighted agreement factors of 0. 047 and 0. 064 for 1610 observed reflections with I≥3δ(I). The results of structure analysis indicate that the framework of this five-coordinated germanium compound is a distorted trigonal bipyramid(TBP).

关 键 词：germatrane distorted trigonal bipyramid crystal structure 2-methylene-succinimide 

分 类 号：O76[理学—晶体学]