ORGANIC PERMSELECTIVE PERVAPORATION CHARACTERISTICS OF POLY(SILYLPROPYNE) AND COPOLYMER DENSE MEMBRANES  

作　　者：王信玮 施艳荞 陈观文 

机构地区：[1]Institute of Chemistry, Academia Sinica, Beijing, 100080

出　　处：《Chinese Journal of Polymer Science》1997年第2期162-171,共10页高分子科学（英文版）

摘　　要：An investigation into the organic permselective separation through poly [1-trimethylsilyl-1-propyne] (PTMSP) and (1-trimethylsily 1)-1-(1-penta-methyl-disily 1)-1-propyne copolymer (TMSP-PMDSP) dense membranes was made to gain an insight into the effect of the chemical structure of membrane materials on pervaporation (PV) characteristics. The results show that the copolymer has a higher separation factor alpha(org/water) but with a relatively lower value of flux J(t) (g/m(2).h) than pure PTMSP. This phenomenon may be attributed to the introduction of side chain with large bulk volume in copolymer, which brought about a decrease of excess free volume and the improvement of diffusion selectivity to some extent. With the same molar concentration of organic liquids in feed, THF/water solutions have the highest value of alpha(org/water) as well as J(t) in comparison with ethanol/water, iso-propanol/water and THF/water mixtures.An investigation into the organic permselective separation through poly [1-trimethylsilyl-1-propyne] (PTMSP) and (1-trimethylsily 1)-1-(1-penta-methyl-disily 1)-1-propyne copolymer (TMSP-PMDSP) dense membranes was made to gain an insight into the effect of the chemical structure of membrane materials on pervaporation (PV) characteristics. The results show that the copolymer has a higher separation factor alpha(org/water) but with a relatively lower value of flux J(t) (g/m(2).h) than pure PTMSP. This phenomenon may be attributed to the introduction of side chain with large bulk volume in copolymer, which brought about a decrease of excess free volume and the improvement of diffusion selectivity to some extent. With the same molar concentration of organic liquids in feed, THF/water solutions have the highest value of alpha(org/water) as well as J(t) in comparison with ethanol/water, iso-propanol/water and THF/water mixtures.

关 键 词：pervaporation separation poly[1-trimethylsilyl-1-propyne] dense membrane organic permselectivity 

分 类 号：TQ320.721[化学工程—合成树脂塑料工业]