一种笼形化合物的合成及工艺改进  

Improved Synithesis of a New Caged Compound

作　　者：董树安[1] 章国贞[1] 

机构地区：[1]山东师范大学化学系,250014

出　　处：《临沂师专学报》1996年第6期19-20,23,共3页

摘　　要：六苄基六氮杂异伍尔兹烷是一种新合成的氮杂笼形化合物，其结构特殊，它的一些衍生物在含能材料等领域得到了广泛的研究．本文在介绍该化合物的合成、形成机理的同时，对其合成工艺进行了改进，用价廉、无毒的乙醇、丙酮等溶剂代替原合成方法中毒性很大的乙腈溶剂，效果良好．Hexabenzylhexaazaisowurtzitane (HBIW) is a kind of new caged compound with special structure, and it has some special properties such as higher density. Some derivatives of HBIW are important enertgetic materials which are being widly studide. The synthetic method of HBIW is improved by using toxicless solvents to replace acetonitrile which was applied in the original method. The reaction conditions and the after-treatment of HBIW have been studied and discussed.

关 键 词：异伍尔兹烷 笼形化合物 合成 

分 类 号：O626[理学—有机化学]