STUDY ON SYNTHESIS, CHARACTERIZATION AND CATALYSIS OF PILLARED ANION CLAY(Ⅲ) ──SYNTHESIS OF ZnAl-BW_(11)O_(39)Z(H_2)￣(n-)  

出　　处：《Chinese Chemical Letters》1995年第7期609-612,共4页中国化学快报（英文版）

摘　　要：ZnAl hydrotalcites have been intercalated by THPOMs (BW11O39Z (H2O)n-(Z=Ni2+, Cu2+ and Al3+) ) via both hydrothermal reaction and ion exchange reaction. The spectra of powder X-ray diffraction and IR show that the synthesized complexes pillared by THPOMs are layered compounds with gallery heights of 9.7～9.9A, The anions entering the layer retain their Keggin structure.ZnAl hydrotalcites have been intercalated by THPOMs (BW11O39Z (H2O)n-(Z=Ni2+, Cu2+ and Al3+) ) via both hydrothermal reaction and ion exchange reaction. The spectra of powder X-ray diffraction and IR show that the synthesized complexes pillared by THPOMs are layered compounds with gallery heights of 9.7～9.9A, The anions entering the layer retain their Keggin structure.

分 类 号：O643.32[理学—物理化学]