STUDIES　ON　THE　NON－ISOTHERMAL　KINETICS　OF　THERMAL　DECOMPOSITIONS　OF　THE　COMPLEXES　OF　Cd（II）WITH　O－VANILLIN　THIOSEMICARBAZONE　AND　IRON（III）WITH　2－［（O－HYDROXYBENZYLIDENE）AMINO］PHENOL　AND　PYRIDINE  

作　　者：Hu, QP Cui, XG Yang, ZH 

机构地区：[1]Shandong Univ, Dept Chem, Jinan 250100, Peoples R China [2]Shandong Univ, Inst Crystal Mat, Jinan 250100, Peoples R China

出　　处：《Chinese Chemical Letters》1995年第7期637-640,共4页中国化学快报（英文版）

摘　　要：The thermal decompositions of the complex of Cd(II) with o-vanillin thiosemicarbazone (complex 1) and the mixed ligand complex of iron (III) with 2-[(o-hydroxybenzylidene)amino] phenol and pyridine (complex 2) and their non-isothermal kinetics have been studied by TG and DTG techniques.The non-isothermal kinetic data were analyzed and the kinetic parameters for the first and second steps of the thermal decompositions were evaluated by twodifferent methods -- differential and integral methods. Their kinetic equatiolls were obtained.The thermal decompositions of the complex of Cd(II) with o-vanillin thiosemicarbazone (complex 1) and the mixed ligand complex of iron (III) with 2-[(o-hydroxybenzylidene)amino] phenol and pyridine (complex 2) and their non-isothermal kinetics have been studied by TG and DTG techniques.The non-isothermal kinetic data were analyzed and the kinetic parameters for the first and second steps of the thermal decompositions were evaluated by twodifferent methods -- differential and integral methods. Their kinetic equatiolls were obtained.

分 类 号：O643[理学—物理化学]