Synthesis and characterization of adducts of p-azidostyrene derivatives to fullerene C_(60)  

作　　者：LI,Ji-Sheng DONG,Guo-Xiao FENG,Jun JI,Gai-JiaoInstitute of Chemistry,Chinese Academy of Sciences,Beijing 100080,China 

出　　处：《Chinese Journal of Chemistry》1995年第6期525-531,共7页中国化学（英文版）

摘　　要： Fullerene C60 reacted with p-azidostyrene derivatives in refluxing chlorobenzene,yielding monoadducts 2a and 2d as well as diadduct 2c with aziridine structure at 6/6-ring junctions.Experimental results showed that the addition of the second azide to the monoadduct was regioselective.The diadduct,of Cs symmetry in C60 moiety,was unstable by opening to be 1,6-imido[10]annulene structure.Fullerene C60 reacted with p-azidostyrene derivatives in refluxing chlorobenzene,yielding monoadducts 2a and 2d as well as diadduct 2c with aziridine structure at 6/6-ring junctions.Experimental results showed that the addition of the second azide to the monoadduct was regioselective.The diadduct,of Cs symmetry in C60 moiety,was unstable by opening to be 1,6-imido[10]annulene structure.

关 键 词：Pullerene azkidine regioselective adduct AZIDE 

分 类 号：O613.71[理学—无机化学]