Comparison between hydrogen-transfer and fluoro-transfer reactions on the microcanonical unimolecular rate constants  

作　　者：Feng, WL Zhang, SW Wang, Y Wu, JN Li, ZH 

机构地区：[1]BEIJING NORMAL UNIV,DEPT CHEM,BEIJING 100875,PEOPLES R CHINA

出　　处：《Chinese Journal of Chemistry》1995年第5期391-395,共5页中国化学（英文版）

基　　金：Project supported by the State Science and Technology Commission of China.

摘　　要：The microcanonical rate constants for the hydrogen-transfer process of HCCF (reaction 7) and the fluoro-transfer process of FCCF (reaction 8) are carried out with tunneling correction and curvature correction. The results show that the tunneling effects and curvature effects on the rate constant of reaction 7 is quite different from that of reaction 8. The rate constants for different rotational states are also studied for these reactions.

关 键 词：microcanonical rate constant tunneling effect curvature correction 

分 类 号：TE621[石油与天然气工程—油气加工工程]