The effects of alkali metal(Na+,K+) on the exchange degree of Hβ zeolite and the catalytic properties of the alkalized zeolites  

作　　者：SHEN, Jian-Ping MA, Jun SUN, Tie JIANG, Da-ZhenDepartment of Chemistry, Jilin University, Changchun, Jilin 130023, ChinaMIN, En-ZeResearch Institute of Petroleum Processing, Beijing 100083, China 

出　　处：《Chinese Journal of Chemistry》1995年第2期124-130,共7页中国化学（英文版）

摘　　要： The effects of alkali metals (Na+,K+) on the exchange degree of Hβ zeolite under different conditions and the conversion of α(or β)-methylnaphthalene over the alkalized zeolites were studied. The results showed that the H+ of Hβ zeolite is totally replaced by the Na+ of NaCl solution, while partially exchanged by the K+ of KC1 solution, there is an exchange equilibrium between the H+ and K+ for Hβ zeolite (Si/Al=17.23) and the value of equilibrium is 88.39. The exchange degree also increases with increasing the Si/Al of the samples. It was suggested that these resluts are attributed to the electrostatic field in the pore of Hβ zeolite and the nature of zeolite and the properties of alkali metal. The isomerization of α(or β)-methylnaphthalene is the main reaction over the samples and it is more favour on the proper acid-base sites of KHβ zeolite.The effects of alkali metals (Na+,K+) on the exchange degree of Hβ zeolite under different conditions and the conversion of α(or β)-methylnaphthalene over the alkalized zeolites were studied. The results showed that the H+ of Hβ zeolite is totally replaced by the Na+ of NaCl solution, while partially exchanged by the K+ of KC1 solution, there is an exchange equilibrium between the H+ and K+ for Hβ zeolite (Si/Al=17.23) and the value of equilibrium is 88.39. The exchange degree also increases with increasing the Si/Al of the samples. It was suggested that these resluts are attributed to the electrostatic field in the pore of Hβ zeolite and the nature of zeolite and the properties of alkali metal. The isomerization of α(or β)-methylnaphthalene is the main reaction over the samples and it is more favour on the proper acid-base sites of KHβ zeolite.

关 键 词：HB zeolite alkali metal exchange METHYLNAPHTHALENE isomerization. 

分 类 号：O643.3[理学—物理化学]