对二异丙苯催化氧化制对二过氧化氢二异丙苯的研究  

The Research of Preparing P-diisopropylbenzene -dihydroperoxids by the Catalytic Oxidation of P-diisopropylbenzene

作　　者：高俊斌[1] 沈力阳[2] 

机构地区：[1]北京石油化工学院化工系 [2]北京化工学院

出　　处：《北京石油化工学院学报》1994年第1期62-64,共3页Journal of Beijing Institute of Petrochemical Technology

摘　　要：制备一系列过渡金属的有机酸盐和有机络合物,并研究它们在对二异丙苯空气氧化制对二过氧化氢二异丙苯反应中的催化性能,用筛选到的具有较好反应活性和选择性的催化剂进行了条件实验,并得出了一个制备对二过氧化氢二异丙苯的较佳工艺。给出了该催化反应的动力学初步分析。In this paper the preparation of a series of organic acid salts and organic complex of transition-metals is dealt with and the catalytic properties of them in the preparing p-diisopropylbenzene-dihydroperoxids by the oxidation of p - diisopropylbenzene with air are studied. The condition experiments were conducted by using the selected catalyst with better reactivity and selectivity and a better process of preparing p-diisopropylbenzene-di-hydroperoxids has been achieved. A primary analysis of the kinetics of catalytic reaction is also given.

关 键 词：对二过氧化氢二异丙苯 过渡金属催化剂 氧化 反应活性 选择性 工艺 动力学 

分 类 号：TQ625[化学工程—精细化工]