Study of Coenzyme B_(12) Model Compounds——CNDO/2 Calculation of C_2H_5Co (SB) and RCo (salen) L Complexes  

作　　者：韩德艳 陈慧兰 缪强 俞马宏 倪浩 唐雯霞 

机构地区：[1]Department of Chemistry, State Key Laboratory of Coordination Chemistry, Nanjing University, Nanjing 210008, PRC Department of Chemistry,Hubei Normal University,Huangshi 435002,PRC [2]Department of Chemistry, State Key Laboratory of Coordination Chemistry, Nanjing University, Nanjing 210008, PRC [3]Department of Chemistry, State Key Laboratory of Coordination Chemistry, Nanjing University, Nanjing 210008, PRC Department of Chemistry,Nanjing University of Science and Technolgy,Nanjing 210014,PRC

出　　处：《Chinese Science Bulletin》1994年第12期1007-1010,共4页

基　　金：Project supported by the National Natural Science Foundation of China.

摘　　要：To synthesize and study the relation between structure and characteristics of Co-Cbond of coenzym B₁₂ model compounds, it is an effective way to understand the fac-tors which can influence the stabilities of Co-C bond and the mechanism of mutasecatalyzed substrate rearrangement. Unfortunately knowledge about micro reaction mecha-nism of the model compounds is limited. W. N. Lipscomb calculated the

关 键 词：COENZYME B12 model compound Co - C BOND BOND order CNDO/2. 

分 类 号：O629[理学—有机化学]