A Modification on the Retention Equation of Liquid-Solid Chromatography lnk' = A + BlnC_(B_1)+CC_(B_1)  被引量:1

A Modification on the Retention Equation of Liquid-Solid Chromatography lnk' = A + BlnC_(B_1)+CC_(B_1)

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作  者:戴朝政 卢佩章 

机构地区:[1]Analysis and Testing Center of Chengdu Branch of Academia Sinica, Chengdu 610041, PRC [2]Dalian Institute of Chemical Physics, Academia Sinica, Dalian 116012, PRC

出  处:《Chinese Science Bulletin》1994年第17期1458-1462,共5页

基  金:Project supported by the National Natural Science Foundation of china.

摘  要:1 Theory Let us consider a liquid-solid adsorbent system. There are two solvents B<sub>0</sub> and B<sub>1</sub> in the liquid phase. B<sub>0</sub> is a weaker solvent and B<sub>1</sub> is a stronger one. By means of statistical thermodynamics and the ideal localized trap model, the adsorption equation of solvent B<sub>0</sub> on the surface of adsorbent phase can be expressed as follows.

关 键 词:CHROMATOGRAPHIC RETENTION EQUATION liquid diromatography ADSORPTION EQUATION HPLC. 

分 类 号:O647.3[理学—物理化学]

 

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