The Synthesis and Crystal Structure of the First Trinuclear Molybdenum Complex Containing PyS Ligands [Mo_3(CO)_6(μ-PyS)_2(μ_3-PyS)_2]  

作　　者：石有茂 陆世维 郭和夫 施剑秋 吴锵金 

机构地区：[1]Dalian Institute of Chemical Physics, Academia Sinica, Dalian 116023, PRC [2]Fujian Institute of Research on the Structure of Matter, Academia Sinica, Fuzhou 350002, PRC

出　　处：《Chinese Science Bulletin》1994年第3期263-264,共2页

基　　金：National Natural Science Foundation of China.

摘　　要：The deprotonated derivative pyridine-2-thiolato （PyS^-） of pyridine-2-thione （PySH）is a potentially amibidentate or multi-functional donor which coordinates toward transitionmetals with either the exocyclic S or heterocyclic N atom or both atoms to form differentcoordination modes. We have recently reported the synthesis and crystal structure ofthe first dinuclear molybdenum complex with doubly-bridging PyS ligands [Mo₂（CO）₄（μ-PyS）₂（PPh₃）₂]which was obtained from the reaction of [Mo（CO）₃（CH₃CN）₃]

关 键 词：Mo3 PyS The Synthesis and Crystal Structure of the First Trinuclear Molybdenum Complex Containing PyS Ligands CO 

分 类 号：O641.4[理学—物理化学]