STUDY ON THE REACTIVITY OF TRICARBONYL(PENTAMETHYL-DISILANYL)CYCLOPENTADIENYL MOLYBDENUM ANION  

作　　者：Xiu Zhong ZHOU Shan Sheng XU Department of Chemistry,Nankai University,Tianjin 300071 Dai Zhi KUANG Department of Chemistry,Hengyang Teachers College,Hunan 421008 

出　　处：《Chinese Chemical Letters》1992年第12期1015-1016,共2页中国化学快报（英文版）

摘　　要：Some reactions of the title anion were studied.By these reactions six molybdenum complexes were prepared.On reac- tion with 1,3-dibromopropane the anion yielded the cyclic carbene complex(η-C_5H_4Si_2Me_5)MoBr(CO)_2CO(CH_2)_2CH_2.The crystal and mole- cular structures of (η-C_5H_4Si_2Me_5)MoBr(CO)_3 and 〔(η-C_5H_4Si_2Me_5)Mo- (CO)_3〕_2 Were determined by X-ray crystallography.Some reactions of the title anion were studied.By these reactions six molybdenum complexes were prepared.On reac- tion with 1,3-dibromopropane the anion yielded the cyclic carbene complex(η-C_5H_4Si_2Me_5)MoBr(CO)_2CO(CH_2)_2CH_2.The crystal and mole- cular structures of (η-C_5H_4Si_2Me_5)MoBr(CO)_3 and 〔(η-C_5H_4Si_2Me_5)Mo- (CO)_3〕_2 Were determined by X-ray crystallography.

关 键 词：Co CSH NBS STUDY ON THE REACTIVITY OF TRICARBONYL PENTAMETHYL-DISILANYL)CYCLOPENTADIENYL MOLYBDENUM ANION 

分 类 号：O6[理学—化学]