~3H—LABELLING OF BELLADONNA ALKALOIDS BY CATALYSED EXCHANGE WITH MICROWAVE EXCITATION  

作　　者：张丽明 郑冬珠 袁建民 蒋晓马 赵夏令 

机构地区：[1]Shanghai Institute of Nuclear Research, Academia Sinica, Shanghai 201800, China

出　　处：《Nuclear Science and Techniques》1992年第3期171-174,共4页核技术（英文）

基　　金：The Project Supported by National Natural Science Foundation of China

摘　　要：The ~3H-labelled belladonna alkaloids obtained by catalysed exchange method with microwave excitation was investigated. The specific activities of the labelled products Were 16—32 TBq/mol. More than 90% labelled positions of these ~3H-tracers were on phenyl rings. The radiochemical purity and chemical purity of crude products were both in 75—80%.The ~3H-labelled belladonna alkaloids obtained by catalysed exchange method with microwave excitation was investigated. The specific activities of the labelled products Were 16—32 TBq/mol. More than 90% labelled positions of these ~3H-tracers were on phenyl rings. The radiochemical purity and chemical purity of crude products were both in 75—80%.

关 键 词：~3H- NMR MICROWAVE catalysed EXCHANGE ~3H-anisodamine hydrobromide ~3H-anisodine ~3H-Atropine sulfate ~3H-scopolamine ~3H-labelling 

分 类 号：TL[核科学技术]