Synthetic Studies on 1-Amino-1-Cyclopropane-Carboxylic Acid( Ⅰ )——The Cyclopropanation via Addition-Elimination Reactions  

作　　者：ZHANG, X. A., Campbell, M. M. and Brown, D. W. (School of Chemistry, University of BATH, U. K. ) 

出　　处：《Chemical Research in Chinese Universities》1992年第4期377-381,共5页高等学校化学研究（英文版）

摘　　要：Various addition-elimination approaches have been explored for diastereoselective construction of 1-amino- 1-cyclopropane-carboxylic acid (ACPC) derivatives, and the desired product was obtained from a reaction of cyclo(NAc-L-Val-NAc-Gly) and methyl α-bro-moacrylate under protonic solvent.Various addition-elimination approaches have been explored for diastereoselective construction of 1-amino- 1-cyclopropane-carboxylic acid (ACPC) derivatives, and the desired product was obtained from a reaction of cyclo(NAc-L-Val-NAc-Gly) and methyl α-bro-moacrylate under protonic solvent.

关 键 词：Synthesis 1-Amino-1-Cyclopropane-Carboxylic acid Addition-elimination reac-tion CYCLOPROPANATION 

分 类 号：O6[理学—化学]