A Theoretical Studies on the Thermolysis Mechanism of α-Aminonitrile  

作　　者：HONG San-guo and LI Fu-quan (Department of Chemistry, Jiangxi Normal University, Nanchang, 330027)FU Xiao-yuan (Department of Chemistry, Beijing Normal University, Beijing, 100875) 

出　　处：《Chemical Research in Chinese Universities》1992年第4期480-482,共3页高等学校化学研究（英文版）

基　　金：Supported by the National Natural Science Foundation of China ; Jiangxi Province.

摘　　要：Introduction α-Aminonitrile(or aminoacetonitrile) is a kind of reactive bioorganic molecules, and it may exist in insterstellar clouds. its importance lies in that a-aminonitrile may play a role in the generation of large carbon-nitrogen chain molecules. By means of flash vacuum thermolysis and gas-solid reaction (FVT-GSR) tech-nique, Guillemin, et al., studied the thermolysis of a-aminonitrile, they considered that the elimination of HCN (shown as following) is a key step in many reactions of α-

关 键 词：THERMOLYSIS α-Aminonitrile Transition state IRC path 

分 类 号：O6[理学—化学]