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机构地区:[1]Department of Analytical Chemistry, Beijing Medical University, Beijing 100083 PRC. [2]Department of Chemistry, Peking University, Beijing 100871 PRC
出 处:《Chinese Science Bulletin》1992年第9期738-741,共4页
基 金:Project supported by the National Natural Science Foundation of China.
摘 要:Studies of electronic transfer reaction involving iron porphyrins are of evident interest because of their importance as biological electronic transfer agents. The electrochemical property of iron porphyrin in nonaqueous media has been extensively investigated by Kadish et al. This note reports the electrochemical behavior of iron porphyrin (Fe-TPPS) in HAc-NaAc buffer solution (3.5【pH【4.2). The reduction of Fe-TPPS gives a sharp
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