STUDIES ON THE STEREOSELECTIVITY AND SUBSTITUTED GROUPS OF (+)-CAMPHOR DERIVATIVES  

作　　者：郭鹏 刘桂兰 蒋耀忠 周忠远 

机构地区：[1]Chengdu Institute of Organic Chemistry, Academia Sinica, Chengdu 610015, PRC [2]Chengdu Center of Analysis and Measurement, Academia Sinica, Chengdu 610015, PRC

出　　处：《Science China Chemistry》1991年第4期385-393,共9页中国科学（化学英文版）

基　　金：Project supported by the National Natural Science Foundation of China.

摘　　要：From (+)- camphor, six new (+)-camphor derivatives were synthesized. According tothe structure and chemical properties of the derivatives, the relation between the substitutedgroups and the stereoselectivity of alkylations and reduction was examined. It is found thatthe chemical shift of protons of C(8), C(9) methyl groups and chemical properties of carbonylO(2) are associated with the substituted groups.From (+)- camphor, six new (+)-camphor derivatives were synthesized. According to the structure and chemical properties of the derivatives, the relation between the substituted groups and the stereoselectivity of alkylations and reduction was examined. It is found that the chemical shift of protons of C(8), C(9) methyl groups and chemical properties of carbonyl O(2) are associated with the substituted groups.

关 键 词：(+)-camphor DERIVATIVES CONFIGURATION STEREOSELECTIVITY 

分 类 号：O6[理学—化学]