MSSBAUER STUDY OF ELECTRON DELOCALIZA-TION OF Fe^(2+) IN JULGOLDITE, A MIXED-VALENCE IRON SILICATE  

MSSBAUER STUDY OF ELECTRON DELOCALIZA-TION OF Fe^(2+) IN JULGOLDITE, A MIXED-VALENCE IRON SILICATE

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作  者:阚学敏 张恩林 李宜荣 SUBRATA GHOSE 

机构地区:[1]Institute of Geochemistry, Academia Sinica, Guiyang 550002, PRC [2]Mineral Physics Group, Department of Geological Sciences, University of Washington, Seattle, WA 98195, USA

出  处:《Chinese Science Bulletin》1991年第20期1729-1733,共5页

摘  要:The general formula of the mineral series of pumpellyite can be written as Ca<sub>2</sub>X<sub>2</sub>·(Y<sub>1-x</sub>Z<sub>x</sub>) Si<sub>3</sub>O<sub>10+x</sub>(OH)<sub>4-x</sub>, where X refers to M (2)sites occupied often by Al<sup>3+</sup>, and Y and Z refer to M (1) sites occupied by Mg and Al respectively. Julgoldite is an iron-rich endmember of the mineral series with an ideal formula Ca<sub>2</sub>Fe<sub>2</sub><sup>3+</sup>(Fe<sub>1-x</sub><sup>2+</sup>Fe<sub>x</sub><sup>3+</sup>)Si<sub>3</sub>O<sub>10+x</sub>(OH)<sub>4-x</sub>·

关 键 词:MSSBAUER ELECTRON DELOCALIZATION julgoldite. 

分 类 号:N[自然科学总论]

 

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