ISOLATION,CHARACTERIZATION AND OXIDATION REACTION OF THE THIRD TYPE OF OXOCHROMIUM(V)TETRAPHENYLPORPHYRIN COMPLEX AS THE ACTIVE INTERMEDIATE IN CYTOCHROME P-450 MODEL SYSTEM  

作　　者：舒火明 谷淑珍 金日镇 刘永盛 金钟声 

机构地区：[1]Changchun Institute of Applied Chemistry, Academia Sinica, Changchun 130022, PRC

出　　处：《Chinese Science Bulletin》1991年第24期2061-2065,共5页

基　　金：Project supported by the National Natural Science Foundation of China

摘　　要：Ⅰ. INTRODUCTION Oxotransition metal porphyrin complexes are possible intermediates in cytochrome P-450 modal system. Several oxotransition metal porphyrin complexes such as titanium (Ⅳ), vanadium (Ⅳ) , molybdenum(Ⅳ, Ⅴ) and chromium (Ⅳ) having been isolated and characterized are not effective oxidizing agents, so they are not possible intermediates

关 键 词：PORPHYRIN oxochromium(Ⅴ) PORPHYRIN COMPLEX 

分 类 号：N[自然科学总论]