TUNNELING CORRECTIONS TO TRANSITION STATE THEORY FOR REACTION H+ H_2(v=0)→H_2(all v)+H  

作　　者：董顺乐 卢兆铭 王燕 

机构地区：[1]Department of Physics, Shandong University, Jinan, 250100, PRC

出　　处：《Chinese Science Bulletin》1991年第3期193-196,共4页

摘　　要：Ⅰ. INTRODUCTIONThe tunneling was not considered in conventional transition state theory (TST). Especially within low reaction temperature the calculation of the conventional TST can bring about obvious errors. In 1979, Kuppermann in his article about TST stressed the state-to-state TST. His theory used the transmission coefficient. On the basis of Kuppermann’s theory it is not difficult to consider the tunneling.

关 键 词：transmission probability transition state PARTITION function. 

分 类 号：N[自然科学总论]