STUDY ON COENZYME B_(12) MODEL COMPOUNDS——IDENTIFICATION OF ALKYL RADICALS IN RCo(Salen)L SOLUTION BY SPIN TRAPPING ESR TECHNIQUE  

作　　者：陈慧兰 钱钺 陈冠菁 唐雯霞 

机构地区：[1]Department of Chenmistry, Nanjing University, Nanjing 210008, PRC [2]Coordination Chemistry Institute of Nanjing University, Nanjing 210008, PRC

出　　处：《Chinese Science Bulletin》1991年第1期42-46,共5页

基　　金：Project supported by the National Natural Science Foundation of China.

摘　　要：Ⅰ. INTRODUCTIONIn our previous studies the cleavage reaction of Co—C bond of RCo（Salen） L [Salen=bis （salicyladehyde）ethylenediamine, L= H₂O or without H₂O, R= CH₃·, C₂H₅·, n-and i-C₃H₇·, n-, i- and t-C₄H₉·] in methanol on photolysis or thermolysis was obtained:

关 键 词：spin trapping ESR TECHNIQUE ALKYL radicals ALKYL cobalt chelate COENZYME B₁₂ model compounds. 

分 类 号：N[自然科学总论]