CARBONACEOUS PRODUCTS OF POLYMER-PALLADIUM COMPLEXES AS CATALYSTS FOR THE HYDROGENATION OF METHYL ACRYLATE  

作　　者：Chun Fu CHEN Jun Tan SUN Hong Li Bing Lin HE Xian Quan GUO Xiu Ping SHI 

机构地区：[1]Institute of Polymer Chemistry,Nankai University,Tianjin 300071

出　　处：《Chinese Chemical Letters》1991年第8期657-658,共2页中国化学快报(英文版)

摘　　要：Many catalysts were pcrpared by carbonization of ion exchange resin-PdCl_2 complexes at high temperature in nitrogen, hydrogen atmosphere. The rates for the hydrogenation of methyl acrylate and the amounts of Pd elution of the carbonaceous products were measured and compared with those of commercial Pd/C catalyst. It indicates that the carbonaceous products are less active than Pd/C. However, the leaching of Pd from carbonaceous products is very small and much less than that from Pd/C.Many catalysts were pcrpared by carbonization of ion exchange resin-PdCl_2 complexes at high temperature in nitrogen, hydrogen atmosphere. The rates for the hydrogenation of methyl acrylate and the amounts of Pd elution of the carbonaceous products were measured and compared with those of commercial Pd/C catalyst. It indicates that the carbonaceous products are less active than Pd/C. However, the leaching of Pd from carbonaceous products is very small and much less than that from Pd/C.

关 键 词：AS CARBONACEOUS PRODUCTS OF POLYMER-PALLADIUM COMPLEXES AS CATALYSTS FOR THE HYDROGENATION OF METHYL ACRYLATE 

分 类 号：O6[理学—化学]