Open metallocenes——Ⅺ. A pentadienyl compound of heavier rare earth element [2,4-(CH_3)_2-η~5-C_5H_5]_3Tb·1/2THF  

作　　者：QIU,Xin LIU,Ju-Zheng 

机构地区：[1]Intitute of Theoretical Chemistry,Jilin University,Changchun 130023

出　　处：《Chinese Journal of Chemistry》1991年第1期10-19,共0页中国化学(英文版)

基　　金：This research was supported by the National Natural Science Foundation of China as an item of major project.

摘　　要：Perfluoroalkyl iodides reacted with conjugated dienes in aqueous acetonitrile solution in the presence of sodium dithionite at room temperature to give dimerization products, whereas, perfluo- roalkanesulfonyl bromides reacted with conjugated dienes to form 1,4-adducts under actinic irradiation.Perfluoroalkyl iodides reacted with conjugated dienes in aqueous acetonitrile solution in the presence of sodium dithionite at room temperature to give dimerization products, whereas, perfluo- roalkanesulfonyl bromides reacted with conjugated dienes to form 1,4-adducts under actinic irradiation.

关 键 词：A pentadienyl compound of heavier rare earth element C5H5 CH3 Open metallocenes THF 

分 类 号：O6[理学—化学]