Electrochemical Study of FeCl3 and FeCl4- in BMImTf2N-dimethylformamide Mixtures  

作　　者：XIE Shu-bao HE Hui ZHANG Qiu-yue HUANG Xiao-hong WU Ji-zong 

机构地区：[1]Department of Radiochemistry

出　　处：《Annual Report of China Institute of Atomic Energy》2013年第1期138-139,共2页中国原子能科学研究院年报（英文版）

基　　金：Supported by National Natural Science Foundation of China(91126022)

摘　　要：Ionic liquids(ILs)as the solvent for electrochemical reaction are different from traditional molecular solvents such as dimethylformamide(DMF).Here we focus on the electrochemistry of FeCl3 and FeCl4-in BMImTf2N-DMF mixtures at different compositions.Firstly,we studied the electrochemistry of FeCl3in pure IL by ultramicroelectrode and observed two waves corresponding to the reduction of FeCl3。

关 键 词：IONIC liquids adding MIXTURES reversible electrolyte LINEARLY supporting partly 

分 类 号：O614.811[理学—无机化学]