一种新型的三维网状结构化合物的合成与晶体结构表征  

Synthesis and Crystal Stucture Characterization of a Compound with Three-Dimensional Network Stuctures

作　　者：赵文华[1] 陈元涛[1] 台夕市[2] 

机构地区：[1]青海师范大学,青海西宁810008 [2]潍坊学院,山东潍坊261061

出　　处：《潍坊学院学报》2013年第4期58-60,共3页Journal of Weifang University

摘　　要：本文以高氯酸钙,3-吲哚丙酸和邻菲罗啉为原料反应合成了一个新的化合物,用X-射线单晶衍射方法对其进行了晶体结构解析。该配合物为单斜晶系,晶胞为P2(1)/c,晶胞参数:a=14.3592(8),b=5.2446(2),c=12.3518(6),β=94.780(2)°,V=926.96(8)3,Z=4,Mr=189.21,Dc=1.356g/cm3,T=296(2)K,F(000)=400,μ(MoKa)=0.094mm-1,R=0.0495,wR=0.1046,S=0.93,化合物通过分子间氢键和π-π堆积作用形成了三维网状结构。A novel compound has been synthesized using 3-Indolepropionic acid,1,10-Phenanthroline monohydrate and Cadmium perchlorate hexahydrate as starting materials,The crystal structure of the compound was determined by X-ray single crystal diffraction.The results showed that the compound was monoclinic,with P2(1)/c,a=14.3592(8),b=5.2446(2), c=12.3518(6),β=94.780(2)°,V=926.96(8)3,Z=4,Mr=189.21,Dc=1.356g/cm3,T=296(2)K,F(000)=400,μ(MoKa)=0.094mm-1,R=0.0495,wR=0.1046,S=0.93.The compound formed three-dimensional network structure through Intermolecule hydrogen bonds andπ-πstacking.

关 键 词：3-吲哚丙酸 化合物 合成 晶体结构 

分 类 号：O641.4[理学—物理化学]