液体接界电位的不可逆过程热力学讨论  

Discussion of Reversible Process Thermodynamics of Liquid junction Equation

作　　者：辛春梅[1] 

机构地区：[1]吉林省教育学院化学系,吉林长春130022

出　　处：《长春师范学院学报》1999年第5期22-24,共3页Journal of Changchun Teachers Coliege

摘　　要：本文从不可逆过程热力学的耗散函数出发，推导了液接电位方程式。结果表明，从不可逆过程热力学理论得到的液接电位方程式与可逆过程热力学理论得到的相同，但前者的推导过程符合液接电位产生的根源。Liquid Junction equation was deduced from the dissipation function of irreversible process thermodynamics. The result shows that liquid junction equation deduced from irreversible process is the same as reversible process thermodynamics, but the former can reflect the root of liquid junction potential, and the latter is not.cussion of Reversible Process Therm odynam ics of Liquid┐junction

关 键 词：不可逆过程 液接电位 液接电位方程式 

分 类 号：O642[理学—物理化学]