定形相变复合材料的研究进展——静电纺丝法  

The Research Progress of Form-Stable Phase Change Composite Materials-Electrospinning

作　　者：蔡以兵[1,2] 孙桂岩[1] 刘盟盟[1,2] 王锦鹏[1] 魏取福[1] 刘伟 

机构地区：[1]生态纺织教育部重点实验室江南大学,无锡214122 [2]江苏箭鹿毛纺股份有限公司,宿迁223800

出　　处：《高分子通报》2015年第2期18-25,共8页Polymer Bulletin

基　　金：中国博士后科学基金(No.2014M560391);国家自然科学基金(No.51006046);国家高技术研究发展计划(863)项目(No.2012AA030313);江南大学大学生创新训练计划项目(No.2013037)

摘　　要：静电纺丝是制备定形相变复合材料的重要方法之一,本文综述了静电纺丝法制备定形相变复合材料的研究进展,主要包括溶液静电纺丝、溶液-溶液同轴静电纺丝、熔融-溶液同轴静电纺丝和静电纺纳米纤维膜物理吸附等,总结了静电纺丝常用的固-液相变材料(如脂肪族长链烷烃、大豆蜡、脂肪酸及其二元低共熔物、脂肪酸酯和聚乙二醇等)和支撑材料(如醋酸纤维素、聚对苯二甲酸乙二醇酯、聚乙烯吡咯烷酮、聚偏氟乙烯、聚乳酸、聚氨酯、聚酰胺6、聚丙烯腈及其碳纳米纤维等)。Electrospinning is one of the important methods for preparing form-stable phase change composite materials.The paper reviews the research progress of form-stable phase change composite materials by electrospinning.The preparation methods mainly include solution electrospinning,solution-solution coaxial electrospinning,melt-solution coaxial electrospinning and physical adsorption of electrospun nanofibrous mats,etc.During electrospinning,the general used solid-liquid phase change materials(e.g.,aliphatic long-chain alkanes,soy wax,fatty acids and their binary fatty acid eutectics,fatty acid esters and polyethylene glycol,etc)and supporting materials(e.g.,cellulose acetate(CA),polyethylene terephthalate(PET),polyvinylpyrrolidone(PVP),polyvinylidene fluoride(PVDF),poly(dl-lactide)(PLA),polyurethane(PU),polyamide 6(PA6),polyacrylonitrile(PAN)and the derived carbon nanofibers,etc)are also summarized.

关 键 词：静电纺丝 定形相变复合材料 纳米纤维 制备方法 

分 类 号：TQ340.64[化学工程—化纤工业]