FI催化剂配体的研究进展  

Advances in the Ligands of FI catalyst

作　　者：吴韦[1] 徐韬[1] 宁英男[1] 毛国梁[1] 姜涛[2] 

机构地区：[1]东北石油大学化学化工学院,大庆163318 [2]天津科技大学材料科学与化学工程学院,天津300457

出　　处：《化学通报》2015年第4期305-311,共7页Chemistry

基　　金：国家自然科学基金项目(20972025和U1362110);中国石油科技创新基金项目(2013D-5006-0503);教育部新世纪优秀人才支持计划(NCET-07-0142)资助

摘　　要：FI催化剂作为一类新型聚烯烃催化剂,具有高活性、耐高温等特性,在催化聚合方面表现出良好的性能,不但可以催化乙烯与极性及非极性单体共聚,而且可以通过改变主催化剂苯氧基亚胺配体的结构,得到具有不同结构的聚合物。本文介绍了FI主催化剂的基本结构、合成方法、结构与催化性能的关系以及基于苯氧基亚胺配体基本结构的新型催化剂的研究进展。As a new type of catalyst used for olefin polymerization,FI catalyst exhibits a good catalytic performance and possesses some characters such as high activity,temperature tolerance etc. It can catalyze the polymerization of ethylene and the copolymerization of ethylene with polar or nonpolar monomers. In addition,the polymers with different structures can be obtained by changing the phenoxy-imine structure of the main catalyst. Herein the structure of FI catalyst complexes,synthesis methods,the relationship between structure and catalytic performance were introduced and the progress in catalyst based on the phenoxy-imine ligand was summarized.

关 键 词：FI催化剂 配体 苯氧基亚胺 聚乙烯 烯烃聚合 

分 类 号：O643.36[理学—物理化学]