1,3,2-二氧磷杂环己烷衍生物的合成  

Synthesis of derivation of 1,3,2-dioxaphosphorinane

作　　者：周少林[1] 张丽萍[1] 万石官[1] 杨兴钰[1] 

机构地区：[1]华中师范大学化学学院,武汉430079

出　　处：《华中师范大学学报（自然科学版）》2004年第2期197-200,共4页Journal of Central China Normal University：Natural Sciences

基　　金：武汉市科技攻关项目(20021002052).

摘　　要：采用5,5-二甲基-2-氯-2-氧-1,3,2-二氧磷杂环己烷和取代苯胺及脂肪二元胺反应,合成了10个未见文献报导的目标化合物 a～ j.通过元素分析、IR、1HNMR、和MS对其结构进行了表征.部分化合物的热重和差热分析表明,化合物最高失重速率的温区在220～400℃,这与大部分高分子材料的热氧降解温区重叠,具有很好的阻燃配伍性能.在醇酸清漆和环氧树脂中的初步阻燃测试表现出很好的阻燃性能.Compound Ⅰ_a～Ⅰ_j were synthesized from 5,5-dimethyl-2-chloro-2-oxo-1,3,2-dioxaphosphosrinane and various amines. The structures of the compounds were confirmed by IR,()~1 H　NMR,MS and elementary analysis. TG and DTA analysis of some of the compounds were discussed. Most of the compounds began to decompose at 220℃ and had certain thermal stability. They decomposed rapidly during 220～400℃ which overlapped with many polymeric material decomposition temperature range. Prelimary test in alkyl resin vernish and epoxy E-44 showed that the compounds had high activity of flame retardance.

关 键 词：环状磷酸酯 膨胀型阻燃剂 合成 

分 类 号：O627.51[理学—有机化学]