CIDNP Study of Photoinduced [2+2] Cycloadditions (the Paterno- Büchi Coupling) of Arylacetylenes and Quinone  

作　　者：Xin Yan WANG Bao Zhen YAN Ting WANG 

机构地区：[1]Department of Applied Chemistry,Beijing University of Chemical Technology,Beijing 100029

出　　处：《Chinese Chemical Letters》2003年第3期270-273,共4页中国化学快报(英文版)

基　　金：Financial support from the National Natural Science Foundation of China (No: 29975002) is gratefully acknowledged.

摘　　要：CIDNP techniques were applied to study the mechanism of photocycloadditions of 2-chloro-5-methoxybenzoquinone 1 with arylacetylenes 2-5 in benzene-d6 and acetonitrile-d6 respectively.CIDNP techniques were applied to study the mechanism of photocycloadditions of 2-chloro-5-methoxybenzoquinone 1 with arylacetylenes 2-5 in benzene-d6 and acetonitrile-d6 respectively.

关 键 词：Paterno-Büchi reaction 1  4-biradicals photo-CIDNP ARYLACETYLENES quinones. 

分 类 号：O621.25[理学—有机化学]