硒芳香杂环化合物的微波固相合成  

Microwave solid-state synthesis of heterocyclic aromatic selenium compounds

作　　者：张俊苓[1] 邹家浩[1] 郑文杰[1] 杨芳[1] 白燕[1] 李毅群[1] 

机构地区：[1]暨南大学化学系,广东广州510632

出　　处：《化学研究与应用》2004年第4期561-562,共2页Chemical Research and Application

基　　金：国家自然科学基金 ( 2 0 2 710 2 2 ) ;广东省自然科学基金资助项目 ( 0 10 3 69)

摘　　要：Under microwave radiation conditions,a series of heterocyclic aromatic selenium compounds of 2,1,3-benzoselena-diazole(BS);1,2,5-selenadiazolo[3.4-b]pyridine(SPb);5-methy1-2,1,3-benzo-[3,4-c]selenadiazole(MB);5,7-dihydroxy-1,2,5-selenadiazolo-[3,4-d]pyrimi dine(DHSP)and 2,1,3-naphtho-[2,3-c]selenadiazole(NS) were synthesized with their respective ortho-aromatic diamines and selenium dioxide,and their yields were between 29% and 84%.The products obtained from the microwave solid-state reactions were characterized by IR,XRD,UV,FS and EA.Under microwave radiation conditions,a series of heterocyclic aromatic selenium compounds of 2,1,3-benzoselena-diazole(BS);1,2,5-selenadiazolo[3.4-b]pyridine(SPb);5-methy1-2,1,3-benzo-[3,4-c]selenadiazole(MB);5,7-dihydroxy-1,2,5-selenadiazolo-[3,4-d]pyrimi dine(DHSP)and 2,1,3-naphtho-[2,3-c]selenadiazole(NS) were synthesized with their respective ortho-aromatic diamines and selenium dioxide,and their yields were between 29% and 84%.The products obtained from the microwave solid-state reactions were characterized by IR,XRD,UV,FS and EA.

关 键 词：硒芳香杂环化合物 硒二唑 微波固相合成 

分 类 号：O621.3[理学—有机化学]