[(Et_4N)_1.5{Li(H_2O)_6}0.5][Cd_2(SC_6H_4Bu^t-4)_6]·C_2H_5OH双核镉配合物的合成与晶体结构  

Synthesis and Crystal Structure of [Et_4N)_(1.5){Li(H_2O)_6}_(0.5)] [Cd_2(SC_6H_4Bu^t-4)_6] · EtOH

作　　者：汤卡罗[1] 李爱群[1] 金祥林[1] 唐有祺[1] 

机构地区：[1]北京大学物理化学研究所,北京1000871

出　　处：《高等学校化学学报》1993年第3期310-313,共4页Chemical Journal of Chinese Universities

基　　金：国家自然科学基金

摘　　要：标题化合物由4-Bu'S_6H_4SLi、Cd(NO_3)2·4H_2O和Et.NBr反应制备。用X射线单晶衍射法测定其晶体结构。The title complex was synthesized and structurally characterized. The crystal belongs to the space group C2/c, α= 5.727(3) nm, 6= 1.2059(3) nm, c=2. 5245(16) nm, β=101.39(5)°, V = 17. 0921(5) nm3, Dc=l. 178 g/cm, Z=8, R=0. 076 for 4692 unique reflections [F≥4. 0σ (F)]. The cadmium is tetrahedral coordination with two terminal and two bridging ligands. The central M2S2 ring is planar and approximately rectangular.

关 键 词：晶体结构 双核络合物 镉络合物 

分 类 号：O614.242[理学—无机化学]