草酸沉淀法制备细颗粒红色荧光粉Y_2O_3∶Eu^(3+)的发光特性  

Luminescent Properties of Small-sized Red Phosphor Y_2O_3∶Eu^(3+) Synthesized by Oxalic Acid Precipitation Method

作　　者：孙曰圣[1] 屈芸[1] 肖监谋[1] 陈达[1] 

机构地区：[1]南昌大学化工系,江西南昌330029

出　　处：《发光学报》2004年第4期359-364,共6页Chinese Journal of Luminescence

基　　金：江西省科技厅重点项目基金资助项目 ( 1999)

摘　　要：对草酸作为沉淀剂制备的细颗粒红色荧光粉Y2 O3 ∶Eu3 + 进行结构和发光特性研究 ,结果表明 :其一次粒径为 2 0～ 30nm ,团聚尺寸D50 =0 .5 3μm。该荧光粉最大激发峰位于 2 5 2 .2nm ,较微米级荧光粉 2 33nm红移了 19.2nm ;最大的发射峰位于 6 12nm ,与微米级的相比几乎没有差别。Eu3 + 离子的掺入构成了发光中心 ,其最佳掺杂的质量分数为 9% ,荧光粉发光的猝灭浓度由微米级的 6 %提高到 9%。由于纳米晶存在表面缺陷和悬挂键 ,其亮度约为微米晶的 70 %左右 ,随着团聚尺寸的增加、煅烧温度的提高和助熔剂的加入 ,荧光粉的发光强度增大。包膜能部分消除表面缺陷和悬挂键 ,提高发光亮度。荧光粉的色坐标为x =0 .6 4 79,y =0 .344 2。Y_2O_3∶Eu^(3+) is a red phosphor with good property. It is usually synthesized by high temperature solid state method. The particle size of the phosphor prepared by this method is lager ,so it must be milled when used. The oxalic acid precipitation method was developed to synthesize non-grinded and small-size red phosphor in our experiment. Firstly, the mixture of Y_2O_3 and Eu_2O_3 was dissolved in nitric acid in certain proportion. Secondly, the prepared oxalic acid solution was placed in a reactor and at the same time a little surfactant was added in it. When the reaction temperature was controlled to be certain value, the nitric acid solution of Y, Eu was added. Afterwards the precipitation formed and then washed, filtrated, dried and calcined to become white Y_2O_3∶Eu^(3+) power. The Luminescent properties of the phosphor were mainly studied . The result shows that the particle diameter is 20～30 nm . The agglomerate size is D_(50) =0.53 μm. The particle is fine and the granularity distribution displays a narrow and normal distribution. The maximum excitation spectrum of the phosphor peaks at λ=252.2 nm, red shift 19.2 nm compared with micro-Y_2O_3∶Eu^(3+). The maximum emission spectrum peaks at λ=612 nm under 254 nm excitation. Compared with the ordinary power of Y_2O_3∶Eu^(3+) , the emission spectrum of the phosphor appears unchangeable. The luminescent intensity increases with growing of agglomerate size. The addition of Eu^(3+) can constitute luminescent centers when Y_2O_3 as basic particle and Eu^(3+)as activator in Y_2O_3∶Eu^(3+) . The less the amount of the added Eu^(3+) is, the lower the luminescent brightness of the phosphor is. The critical concentration of Eu^(3+) increases from 6% for micro-Y_2O_3∶Eu^(3+) to 9% for nano-Y_2O_3∶Eu^(3+). The phosphor shows a relative luminescent brightness about 70% of that of the micro-Y_2O_3∶Eu^(3+), because of the existence of hanging-bonds and defects on the surface of nano-Y_2O_3∶Eu^(3+) particles. The phosphor particle was increas

关 键 词：草酸沉淀 细颗粒 荧光粉 Y2O3:Eu^3+ 发光 

分 类 号：O482.31[理学—固体物理]