固相配位化学反应研究(LXI)——[Cu(SC(Ph)NHPh)(PPh_3)_2X](X+Cl,Br,I)的固相合成和晶体结构(X=Cl)  

Studies on the Solid State Reaction of Coordination .Compounds (LXI) --Solid State Synthesis of [Cu(SC(Ph)NHPh)(PPh_3)_2X](X = Cl, Br, I) and Crystal Structures of [Cu(SC(Ph)NHPh)(PPh_3)_2Cl]

作　　者：郎建平[1] 鲍时安[1] 忻新泉[1] 蔡进华[2] 康北笙[2] 

机构地区：[1]南京大学配位化学国家重点实验室,南京210008 [2]中国科学院福建物质结构研究所

出　　处：《高等学校化学学报》1993年第6期750-754,共5页Chemical Journal of Chinese Universities

基　　金：国家自然科学基金;国家教委博士点基金

摘　　要：SC(Ph)NHPh,CuX(X=Cl,Br,I)和PPh_3的固相反应产物经CS_2处理得红黄色立方晶体[Cu(SC(Ph)NHPh)(PPh_3)_2X],其中X=Cl的单晶用X射线衍射法收集晶胞参数,此晶体属单斜晶系,空间群P2_1/c,α=1.8013(5)nm,b=1.4588(5)nm,c=1.7222(4)nm,β=105.54(3)°,F=4.3601nm^3,Z=4。中心铜离子以扭曲四面体配位,Cu原子周围的平均键角为109.4°,其中Cu—S键、Cu—Cl键、Cu—P(1)键和Cu—P(2)键的键长分别为0.2352(3)nm、0.2375(4)nm、0.2297(4)nm和0.2282(3)nm.A reddish-yellow solid was produced by the solid state reaction of SC(PH)NHPh, CuX(X = Cl,Br,I) and PPh3. The products were extracted with CS2 to obtain the reddish-yellow cubic crystals [Cu(SC(Ph)NHPh)(PPh3)2X]. The crystal (X = C1) is monoclinic with α=1. 8013(5) nm, 6=1.4588(5) nm, c=1. 7222(5) nm;β=105. 54(3)°, space group P21/c, Z=-4. The geometry of the central Cu(Ⅰ) ion is distorted tetrahedron configuration. The average bond angle about the Cu(Ⅰ) ion is 109. 4% Cu-S, Cu- Cl, Cu-P(1) and Cu--P(2) distances are 0. 2352(3) nm, 0. 2375(4) nm, 0. 2297(4) nm and 0. 2282(3) nm, respectively.

关 键 词：含硫配体 铜配合物 固相合成 

分 类 号：O614.121[理学—无机化学]