甲醇气相直接氧化羰基化合成碳酸二甲酯的研究进展  被引量：8

nthesis of DMC by Vapor-Phase Oxidative Carbonylation of Methanol</em> <p class='article-op'> <span id="bdshare" class="bdshare_t bds_tools get-codes-bdshare baidufx"><span><span class="bds_more" style="display: block; width: 62px; height: 29px; background: url(/images/share.gif) no-repeat!important; padding: 0;"></span></span></span> </p> <p class="article-source"> <a href ='/article/read.aspx?id=10346919' class='btnTitle btnIsView' target='_blank'><img alt='在线阅读' src='/images/btn-read.png'/></a><a class='btnTitle btnIsView' href="javascript:showdown('12aE013l9ZYPTwDd2zEYd3hrPCwPwJ5BzC+onwMDfcc=')"><img alt="下载全文" src="/images/btn-down.png" /></a> <input id="hiddowninfo" type="hidden" value="12aE013l9ZYPTwDd2zEYd3hrPCwPwJ5BzC+onwMDfcc="/> </p> <div class="collect" style="display: none"> <h5>我的收藏</h5> <div class="cnt"> <p> 名 称：<input type="text" name="collTitle" id="collSumTitle" /> </p> <p> 注 释：<input type="text" name="collRemark" id="collSumRemark" /> </p> <p style="text-align: center;"> <a href="javascript:void(0)" onclick="g_collectSumOk();"> <img width="65" height="17" src="/images_new/collect_ok.png" alt="完成" /></a> <a href="javascript:void(0)" onclick="g_collectSumCancel();"> <img width="65" height="17" src="/images_new/collect_no.png" alt="取消" /></a> </p> </div> </div> </div> <form name="wxTransfer" method="post"> <input type="hidden" name="lid" value="" /> <input type="hidden" name="sip" value="" /> <input type="hidden" name="date" value="" /> <input type="hidden" name="co" value="" /> <input type="hidden" name="Title_C" value="" /> <input type="hidden" name="Writers" value="" /> <input type="hidden" name="Name_C" value="" /> <input type="hidden" name="Num" value="" /> <input type="hidden" name="Years" value="" /> <input type="hidden" name="Volumn" value="" /> <input type="hidden" name="GCH" value="" /> <input type="hidden" name="Vol" value="" /> <input type="hidden" name="BookID" value="" /> <input type="hidden" name="SubjectNum" value="" /> <input type="hidden" name="SpecialNum" value="" /> <input type="hidden" name="mirrorName" value="" /> <input type="hidden" name="UserID" value="" /> <input type="hidden" name="UserName" value="" /> <input type="hidden" name="sourceID" value="" /> </form> <script type="text/javascript" src="/scripts/transfer.min.js"></script> <div class="article-detail"> <p class='author'><strong>作　　者：</strong><a href='/writer/article.aspx?id=100000008453512' target='_blank' ><b class='type_ico_id'></b></a><a href='/zk/search.aspx?key=A%3d%5b%e6%9d%8e%e8%8c%9c%5d' title='李茜[1]'>李茜[1]</a> <a href='/writer/article.aspx?id=100000004841974' target='_blank' ><b class='type_ico_id'></b></a><a href='/zk/search.aspx?key=A%3d%5b%e6%9d%8e%e5%bf%a0%5d' title='李忠[1]'>李忠[1]</a> <a href='/writer/article.aspx?id=100000002443566' target='_blank' ><b class='type_ico_id'></b></a><a href='/zk/search.aspx?key=A%3d%5b%e8%b0%a2%e5%85%8b%e6%98%8c%5d' title='谢克昌[1]'>谢克昌[1]</a> <em> </em></p><p class='organ'><strong>机构地区：</strong><a href='/organ/article.aspx?id=50417&subid=&showname=&searchtype=' target='_blank'><b class='type_ico_id'></b></a><a href='/zk/search.aspx?key=S%3d%e5%a4%aa%e5%8e%9f%e7%90%86%e5%b7%a5%e5%a4%a7%e5%ad%a6+%e7%85%a4%e7%a7%91%e5%ad%a6%e4%b8%8e%e6%8a%80%e6%9c%af%e6%95%99%e8%82%b2%e9%83%a8%e5%92%8c%e5%b1%b1%e8%a5%bf%e7%9c%81%e9%87%8d%e7%82%b9%e5%ae%9e%e9%aa%8c%e5%ae%a4' title='[1]太原理工大学 煤科学与技术教育部和山西省重点实验室,山西太原030024'>[1]太原理工大学 煤科学与技术教育部和山西省重点实验室,山西太原030024</a> <em> </em></p><p class='from'><strong>出　　处：</strong><a href='/journal/summary.aspx?gch=92242X' target='_blank'><b class='type_ico_id'></b></a><a href='/zk/search.aspx?key=J%3d%5b%e7%9f%b3%e6%b2%b9%e5%8c%96%e5%b7%a5%5d' title='石油化工'>《石油化工》</a>2004年第7期677-683,共7页<em>Petrochemical Technology</em></p><p class='fund'><strong>基　　金：</strong>山西省归国留学基金(2003-31)山西省自然科学基金(20031022)资助项目。</p><p class='abstrack'><strong>摘　　要：</strong>对甲醇气相直接氧化羰基化合成碳酸二甲酯反应的热力学以及反应中所使用的各种催化剂的制备、性能及催化机理进行了总结和分析。CuCl2／AC、Wacker型和CuI／分子筛催化剂是该反应使用的主要催化剂,其中CuI／分子筛催化剂可以在无氯存在下进行催化作用,避免了对设备的腐蚀,且活性和稳定性都比较好,有望成为该反应催化剂进一步研究的方向。<em><abstract>Cl2/AC, Wacker and CuI /molecular sieve as important catalysts have been dramatically studied these years in gas-phase oxidative carbonylation of methanol to DMC. This is a thermodynamically favorable reaction. The preparation, catalytic properties and catalytic mechanism of these catalysts were reviewed and discussed.CuI/zeolite catalyst not only has a good stability and selectivity but can avoid erosion of reactors due to absence of chloride,and thus has a prosperous future.</em></p><p class='subject'><strong>关 键 词：</strong><a href='/subject/article.aspx?id=2516407' target='_blank'><b class='type_ico_id'></b></a><a href='/zk/search.aspx?key=K%3d%5b%e7%a2%b3%e9%85%b8%e4%ba%8c%e7%94%b2%e9%85%af%5d' title='碳酸二甲酯'>碳酸二甲酯</a> <a href='/subject/article.aspx?id=847266' target='_blank'><b class='type_ico_id'></b></a><a href='/zk/search.aspx?key=K%3d%5b%e6%b0%a7%e5%8c%96%e7%be%b0%e5%9f%ba%e5%8c%96%5d' title='氧化羰基化'>氧化羰基化</a> <a href='/subject/article.aspx?id=5808941' target='_blank'><b class='type_ico_id'></b></a><a href='/zk/search.aspx?key=K%3d%5b%e7%94%b2%e9%86%87%5d' title='甲醇'>甲醇</a> <a href='/subject/article.aspx?id=3273918' target='_blank'><b class='type_ico_id'></b></a><a href='/zk/search.aspx?key=K%3d%5b%e7%83%ad%e5%8a%9b%e5%ad%a6%5d' title='热力学'>热力学</a> <a href='/subject/article.aspx?id=2657568' target='_blank'><b class='type_ico_id'></b></a><a href='/zk/search.aspx?key=K%3d%5b%e9%93%9c%e5%82%ac%e5%8c%96%e5%89%82%5d' title='铜催化剂'>铜催化剂</a> </p><p class='class'><strong>分 类 号：</strong><a href='/zk/search.aspx?key=C%3dTQ225.52' title='TQ225.52'>TQ225.52</a>[<a href = '/domain/article.aspx?id=126' >化学工程—有机化工</a>] </p> </div> <div id="content_wzxg" name="wzxg" class="article-graph"> <object width="695" height="250" classid="clsid:D27CDB6E-AE6D-11cf-96B8-444553540000" id="FlashID"> <param value="../flash/relation.swf" name="movie"> <param value="high" name="quality"> <param value="opaque" name="wmode"> <param value="6.0.65.0" name="swfversion"> <param value="dataUrl=/ajax/articlerelativegraph.ashx?id=10346919" name="flashVars"> <embed width="695" height="250" src="../flash/relation.swf" type="application/x-shockwave-flash" quality="high" wmode="opaque" 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