聚合物载体-稀土金属络合物的研究 Ⅸ.聚(苯乙烯-丙烯酰胺)载体-钕络合物的合成、表征及其催化活性  

Research on Polymer-Supported Rare Earth Metal Complexes Ⅸ. Synthesis, Characterization and Catalytic Activity of Rare Earth Metal Complex Supported on Polymer Containing Amide Groups

作　　者：李玉良[1] 于广谦[1] 朱永楷[1] 宋宏升 

机构地区：[1]中国科学院长春应用化学研究所,长春130022

出　　处：《功能高分子学报》1993年第2期139-142,共4页Journal of Functional Polymers

基　　金：国家自然科学基金

摘　　要：本文介绍了一种新的聚合物载体-稀土金属络合物,聚(苯乙烯-丙烯酰胺)载体-钕络合物的合成,表征和讨论了络合物的IR光谱,由此络合物与烷基铝组成的二元体系对丁二烯聚合具有良好的催化活性和定向效应。不同烷基铝的催化活性顺序为Al(i-Bu)_3>Al(i-Bu)_2H>AlEt_3。A new poly(styrene-co-acrylamide)—supported NdCl_3 complex has been prepared. The characteristics and the IR spectrum of the complex are discussed. The binary systems formed from polymer-supported NdCl_3 complex in combination with aluminum alkyls show good catalytic activity and stereospecificity for butadiene polymerization. For aluminum alkyls, the following order of activity was found:Al(i-Bu)_3 > Al(i-Bu)_2H > AlEt_3.

关 键 词：聚合 稀土元素 载体 催化剂 丁二烯 

分 类 号：O643.36[理学—物理化学]