甲壳胺的结晶度和结晶形态  

Crystallinity and Crystalline Morphology of Chitosan

作　　者：莫秀梅[1] 周涵新 孙桐[2] 

机构地区：[1]华东化工学院高分子材料系,上海200237 [2]中国纺织大学化纤系,上海200051

出　　处：《功能高分子学报》1993年第2期117-122,共6页Journal of Functional Polymers

基　　金：国家自然科学基金

摘　　要：首次制得非晶甲壳胺样品,并给出了根据X射线衍射图精确计算甲壳胺结晶度的公式,计算得知甲壳胺的结晶度随脱酰度的增加(74%～85%)而增加,发现甲壳胺的结晶结构和结晶形态与制样条件有关。For the first time amorphous chitosan have been prepared. An equation has been given to calculate the crystallinity of chitosan, based on the X-ray diffraction intensity of amorphous chitosan. The crystallinity increases with the increasing of deacetylation degree of chitosan from 74% to 86%. The crystalline morphology of chitosan measured by both polaroid optical microscope and small angle light scattering are varied with the processing condition.

关 键 词：结晶度 晶体形态学 壳聚糖 

分 类 号：O636.1[理学—高分子化学]