二(β-甲氧甲酰乙基)二氯化锡工业化生产工艺的研究  

Studies on Industrial Process of Bis(β-methoxycarbonylethyl)tin Dichlorides

作　　者：张书华[1] 王虹[1] 赵春山[1] 李佩瑾[1] 秦伟艳[1] 

机构地区：[1]哈尔滨理工大学化学与环境工程学院,黑龙江哈尔滨150040

出　　处：《哈尔滨理工大学学报》2004年第4期127-129,共3页Journal of Harbin University of Science and Technology

基　　金：黑龙江省教育厅科学技术研究项目(10531058)

摘　　要：研究了以混合溶剂法生产酯基锡热稳定剂的中间体-二(β-甲氧甲酰乙基)二氯化锡的工艺路线,采用正交设计法对混合溶剂的体积分数和影响反应的工艺因素进行了研究,确定了合成路线,并用二(β-甲氧甲酰乙基)二氯化锡与巯基乙酸异辛酯反应合成了酯基锡热稳定剂,对其主要性能进行了测试,结果表明,合成路线为两种溶剂的体积分数比为80％:20％(三氯甲烷:四氢呋喃),反应时间为5h,反应温度为20～25℃;热稳定剂的热稳定时间达41min。In this article, a new industrial process of bis(β-methoxycarbonylethyl) tin dichlorides by means of mixing solvent is studied. The research on the ratio of the two solvent and the major technological factors affecting reaction is carried out by the methods of orthogonal design. The process for industrial manufacture is determined. And ester-tin stabilizer is prepared by reacting of bis (β-alkoxycarbonylethyl)tin dichlorides and i-octyl thioacetate. Finally, the main properties are tested, thermal stability time is 41min. The volume ration of the two solvent is 80%:20%(chloroform: tetrahydrofuran), the reaction time is 5h, the reaction temperature is 20～25℃.

关 键 词：酯基锡 二(β-甲氧甲酰乙基)二氯化锡 混合溶剂 工业生产工艺 

分 类 号：TQ047.4[化学工程]